|Three different-sized clusters with very different structures|
Water clusters are assemblies of water molecules that are held together by intermolecular hydrogen bonds. Until now, most studies have focused on small clusters with 12 molecules or less and the structure of these objects bears little resemblance to bulk ice. In the past few years, researchers in Japan have developed a spectroscopy-based technique to probe water clusters containing up to 50 molecules. However, detailed structural analysis of clusters with 100–1000 molecules, where ice crystallization was thought to occur, was beyond the reach of these studies.
The main difficulty in analysing large water clusters is knowing exactly how many molecules they contain. This is done by mass spectrometry, which involves ionizing the clusters by hitting them with high-energy radiation, which can smash the delicate clusters into fragments. Furthermore, researchers would rather study neutral than charged water clusters because these are involved in most of the ice-crystallization processes in nature.
Doped water clustersNow, researchers including Thomas Zeuch at the Institut für Physikalische Chemie in Göttingen, Germany, have found a way to analyse neutral water clusters containing hundreds of molecules. Their success lies in two clever tricks. First, each water cluster is doped with a single sodium atom. Using this highly reactive metal means that the doped water clusters are ionized more easily than pure clusters and ensures that the electron is liberated from the sodium atom rather than the neutral water cluster.
Second, before being ionized, the doped clusters are excited with infrared radiation. This increases their temperature, thereby altering their structure in such a way that further lowers their ionization potential. The clusters can then be ionized with a 390 nm ultraviolet laser, which has low-enough energy to avoid fragmentation. The sizes of these ionized water clusters are determined using time-of-flight (TOF) mass spectrometry.
Then, in order to probe their structure, the infrared spectra of the water clusters are calculated. Infrared radiation with wavenumbers between 2800 and 3800 cm–1 is used, corresponding to the vibrational (stretching) frequencies of oxygen–hydrogen bonds. This vibrational spectroscopy provides an insight into the arrangement of water molecules inside the cluster. For instance, it is known that crystalline ice has an absorption maximum at wavenumbers around 3200 cm–1, whereas amorphous ice and liquid water have maxima at approximately 3400 cm–1.